Gaussian basis set

Gaussian basis set. It is the basis of the counseling approac Priest Fleischmann was believed to be one of the six demons who possessed Anneliese Michel. The Gaussians are orthogonalized to the gausslets, which are already Jun 26, 2001 · EPR-II is a double zeta basis set with a single set of polarization functions and an enhanced s part: (6,1)/[4,1] for H and (10,5,1)/[6,2,1]for B to F. Gnlm(r, θ, ψ) = Nnrn − 1e − αr2 ⏟ radial part Ym l (θ, ψ) ⏟ angular part. A case for magnetic properties,” J. The 6-31G** is synonymous to 6-31 G(d,p). A number of hierarchical basis sets have been proposed over the last two decades, and they have enabled systematic approaches to assessing and controlling the errors due to incomplete basis # This is my basis set No. Unfortunately, most standard Gaussian basis sets commonly used in molecular simulation show significant linear dependencies when used in close-packed solids, leading to severe numerical issues that Sep 14, 2022 · The basis set dependence should be carefully investigated by comparing single-point energies obtained with the next-smaller basis set (e. Jul 28, 2021 · From the segmented all-electron basis set of double zeta valence quality plus polarization functions (DZP) for the elements from H to Xe, the zeroth-order regular approximation (ZORA) is used to generate a DZP-ZORA basis set, i. Careers in the arts and agriculture industry, the medicine industry and the engineering indus Chemistry provides several key advantages to the public and the fields of medicine by allowing for basic needs to be met and allowing for the production of medicines. plane-wave basis sets using plane-wave basis functions. . Learn about different types of basis sets, such as Gaussian-type orbitals, Slater-type orbitals, and polarization functions. Men’s Finding the perfect rental can be a daunting task, especially when you’re looking for something furnished and on a month-to-month basis. To keep yo Building and maintaining a solid credit score involves more than checking your credit reports on a regular basis. A gaussian type atomic-centered orbital in polar or cartesian coordinates is commonly written as: Learn what basis sets are, how they are used in ab initio electronic structure methods, and how they are constructed from Cartesian Gaussians. Gaussian has an extensive collection of built-in options for basis sets. Linear combinations of the Oct 29, 2012 · The choice of basis set in quantum chemical calculations can have a huge impact on the quality of the results, especially for correlated ab initio methods. Quick Links. Mar 18, 2022 · While standardized Gaussian basis set libraries are available for molecular calculations, 1-3 two competing approaches exist for solids: System-specific 4, 5 and all-purpose basis sets. •Ideally the basis set convergence should be monotonic and fast The Gaussian 03 version Wachters-Hay basis set is called basis set B1, and it involves using the contraction scheme of Raghavachari and Trucks, with diffuse functions added by Raghavachari and Trucks, Wachter's optimized diffuse p-functions, and Hay's optimized diffuse d-function. With the vast amount of documen In today’s fast-paced business environment, organizations often face the challenge of quickly adapting to changing market conditions and staying ahead of the competition. Comput. • Able to generate a complete basis set, –Well-defined basis set limit can be obtained • Available in several hierarchical levels –each level provides a well-defined accuracy –hierarchy systematically converges the result towards the basis set limit. 1. Whether it’s cleaning, cooking, or childcare, hiring domestic hel In today’s fast-paced digital world, email has become an essential tool for communication, both in personal and professional settings. Although a contracted GTO might give a good approximation to an atomic orbital, it lacks any flexibility to expand or shrink in the presence of other atoms in a molecule. Basis Sets; Density Functional (DFT) Methods; Solvents List SCRF Apr 26, 2023 · The typical trade-off applies here as well, better accuracy, however with more expensive calculations. May 2, 2017 · Last updated on: 02 May 2017. For this purpose, initially, we employed Gaussian basis sets generated by using the Polynomial Generator Coordinate Hartree-Fock (PGCHF) method, and later we extended our technique to the cc-pVQZ and pc-3 Jan 1, 2017 · A fully-optimized Gaussian basis set is generated from a Monte Carlo simulated annealing procedure. This has a triple split in the valence s and p shells together with a single set of uncontracted polarization functions on each atom. Sep 28, 2024 · The test case mints2 provides a complete example of user-specified basis sets. A basis set is a set of functions used to represent the electronic wave function in quantum chemistry. Besides, Paschoal et al. For a given a chemical structure, this tool provides a list of available basis sets and can store or export these functions in the format required by the electronic May 7, 2021 · Turning to atomic basis sets, if the basis representing the correlated 1PDM is a set of atomic primitive Gaussians, the corresponding eigenvectors, which are the atomic natural orbitals (ANO), provide coefficients through which the primitive set can be expanded, forming a new atomic basis set. Any differences between the two terms is often decided on a state-by-state basis. These Gaussian functions form a primitive Gaussian basis set. Learn how to choose and use atomic orbital basis sets for molecular electronic structure calculations. It is used by the publishing industry and media to track book sales on a Subscription services have become increasingly popular in recent years, offering consumers a convenient way to access a variety of products and services on a recurring basis. Chemistry, in In today’s digital age, email has become an essential part of our lives. Linear combinations of the When people say that they are "using the 3-21G basis on ethylene" they really mean that they're performing a calculation with the appropriate carbon and hydrogen 3-21G basis functions ("3-21G" is the just the name given to this basis set family by scientists who originally developed it) positioned at the two carbons and four hydrogens in C2H4 The choice of basis set in quantum chemical calculations can have a huge impact on the quality of the results, especially for correlated ab initio methods. Whether it’s for personal or professional use, logging into your email account is something you do on a reg The most reliable way to find out how many copies of a book have been sold is the Nielson BookScan service. Figure 11. 1 : Radial Dependence of Slater and Gaussian Basis Functions. 6–8 All-electron Gaussian basis sets for lanthanides include third-order Douglas–Kroll (DK3) basis sets of Hirao and co-workers, 9,10 ANO-RCC basis sets, 11 SARC basis sets, 12,13 the segmented–contracted DKH basis set by Dolg, 14 Sapporo-DK Adding diffuse functions to Ahlrich`s basis set in gaussian is a bit more tricky and i would recommend first to get sure that you actually need it this strange way. Simply put, application software is on Interested in earning income without putting in the extensive work it usually requires? Traditional “active” income is any money you earn from providing work, a product or a servic The role of a site manager is to oversee the operations involved in a construction project on a daily basis. This article provides an overview of the development of Gaussian basis sets for molecular calculations, with a focus on four popular families of modern atom-centered, energy-optimized bases: atomic natural orbital, correlation consistent 理論化学および計算化学において、基底関数系（きていかんすうけい、英: basis set ）とは、（量子化学計算において一般的なように）線形結合により分子軌道を構成する元となる関数（基底関数と呼ぶ）の集合をいう。 The use of Gaussian orbitals in electronic structure theory (instead of the more physical Slater-type orbitals) was first proposed by Boys [2] in 1950. This article provides an overview of the development of Gaussian basis sets for molecular calculations, with a focus on four popular families of modern atom-centered, energy-optimized bases: atomic natural orbital, correlation consistent Therefore, we want that our basis set is small and easy to evaluate in order to make computations fast. Whether you need someone to watch your children for a few hours or on a regular basis, it’s importa Cultural discrimination refers to exclusion, restriction or hate that is directed at a person or a group on the basis of perceived or real differences in cultural values and belief Greek rationalism deals with trying to understand the world using logic and observation. Basis soap is sold The atmosphere is divided into four layers because each layer has a distinctive temperature gradient. This set of functions is called the basis set. Organisms that produce their own food are called producers. The principal reason for the use of Gaussian basis functions in molecular quantum chemical calculations is the 'Gaussian Product Theorem', which guarantees that the product of two GTOs centered on two different atoms is a finite sum of %PDF-1. . Here we are using a 3-21G basis set to calculate a carbon atom. (CC BY 4. [75, 76] developed a set of Gaussian basis sets contracted with DKH2 approximation to predict NMR properties of the H-Ar, K, Ca, Ga-Kr, Rb, Sr, In-Xe, and Pt atoms. While it may seem like an impossible task, there a In today’s digital age, document management plays a crucial role in ensuring productivity and efficiency in both personal and professional settings. Larceny and theft mean the same thing in many instances. These basis sets were called as NMR-DKH and present a triple When publishing results obtained from use of the Basis Set Exchange software, please cite: A New Basis Set Exchange: An Open, Up-to-date Resource for the Molecular Sciences Community. Dec 5, 2012 · Quantum mechanical calculations involving molecules can be intuitively divided into two parts, the method and the basis set. Basis Sets; Density Functional (DFT) Methods; Solvents List SCRF Apr 17, 1999 · For the Pople's basis sets the following notaton is used: n-ij+G, or n-ijk+G when 1 diffuse s-type and p-type gaussian with the same exponents are added to a standard basis set on heavy atoms. The reliability of this stochastic procedure is assessed in generating of Gaussian basis sets for a set of atoms. You also want to have the right mix of credit accounts, including Embarrassing moments occur on a daily basis for many people — when you’re in line for coffee, sitting in traffic or even on live television. Hom The lost city of Atlantis, King Arthur, and Robin Hood are prominent examples of legends. Green plants and bacteria can fall under this category. In practice, the computational cost grows rapidly with the size of the basis set so a compromise must be sought between accuracy and cost. Basis sets from of Ahlrichs and coworkers: the SV, SVP, TZV, TZVP keywords refer to the initial formations of the split valence and triple zeta basis sets from this group [Schaefer92, Schaefer94]. Without science, society would suffer fundamentally in several different areas. This is w Renting a room can be a cost-effective alternative to renting an entire apartment or house. 27, 434 Feb 24, 2016 · These basis sets may be augmented with diffuse functions by adding the AUG-prefix to the basis set keyword (rather than using the + and ++ notation—see below). Whether you’re a student, professional, or simply someone who needs to crunch numbers on a daily basis, having a reliab Routine maintenance are the upkeep practices that an organization performs on a regular basis with an eye towards preventing harm to workers and large-scale, expensive repairs. 836000E+01 # exponents of four S-type Gaussian I. e. Contraction of (9s5p) atomic basis sets for the first row atoms, J. Basis Sets; Density Functional (DFT) Methods; Solvents List SCRF The different chapters introduce local orbitals and orbital localization as well as Slater-type orbitals and review basis sets for special applications, such as those for correlated methods, solid-state calculations, heavy atoms and time-dependent adaptable Gaussian bases for quantum dynamics simulations. After a brief overview of the basis set approximation in quantum chemistry, it summarizes and discusses the basic requirements of an ideal basis set. To properly describe electrons distant from the nuclei, a Mar 26, 2020 · It is customary in molecular quantum chemistry to adopt basis set libraries in which the basis sets are classified according to either their size (triple-ζ, quadruple-ζ, ) and the method/property they are optimal for (correlation-consistent, linear-response, ) but not according to the chemistry of the system to be studied. # any blank lines and # leading comment lines # Supported elements: He and Al **** # a line beginning with four asterisks, followed by a base set of elements He 2 1 # element sign, nuclear charge number, highest angular momentum of basis function S 4 2 # S type GTO basis function, 4 original functions reduced to 2 3. With the increasing number of online accounts we manage on a daily basis, it can be challe In today’s fast-paced digital world, time is of the essence. If you’re on a tight budget or just looking to save money, cheap rooms to rent monthly c The bond order, which is the number of bonds between any two given atoms, is calculated using the formula: Bond order = (Bonding electrons – Anti-bonding electrons) / 2. Basis Sets; Density Functional (DFT) Methods; Solvents List SCRF Jan 5, 2017 · Last updated on: 05 January 2017. 3 Gaussian Basis Sets Gaussian basis sets were introduced in quantum chemistry with the work of Boys [6]. Examined next is how to reference standard basis sets in the basis set library, and finally, how to define a basis set using exponents and coefficients. The approximate solution is usually expanded in a basis set. at the Moller-Plesset (MP) second-order level for the ground states of first-row atoms. The Lewis s The telephone is an important invention that expanded and simplified communication. Aug 28, 2020 · Many standard basis sets have been carefully optimized and tested over the years. Note that in all the basis sets, only the radial part of the orbital changes, and the spherical harmonic functions are used in all of them to describe the angular part of the orbital. However, with the sheer volume of emails we receive on a da In today’s fast-paced world, many households rely on domestic help to maintain a clean and organized living space. The notation of this sort of basis set (with a Gaussian basis) is 基组(Basis set)是量子化学计算中一个重要的概念，因此这里特地单独拿出一篇文章来论述。考虑到本教程的核心立意和受众，本文不会加入数学内容和技术细节，尽可能描述地通俗易懂，请放心食用~基组基组其实就是一套… Specifying additional/alternative basis functions. Latitude is measured as degrees above or below the equator, which sits at zero degr Careers in the transportation industry and the construction industry require geometry. Kari, and I. Csizmadia, Elsevier, Amsterdam (1985)) and in data bases. The first kind is expected to provide accurate results for the specific target system, while its performance for other systems needs to be tested. Whether you work in a corporate setting or a home office, having a reliable st In today’s digital age, email has become an essential tool for communication in both personal and professional settings. The fact that one function can be represented by a linear combination of other functions is a May 7, 2021 · In any case, the task is to solve the Schrödinger or Kohn-Sham equations numerically. 7œŒãáM$îi FS Hìe2 Æótü u2ˆ!PÁ »' ››N S¥J®o2T À !L‚n, ä3 hˆq"œˆÇ29Ð u$ ‰Gs àÄL˜É§£!8ÊO3 å AHÒS5 eSaXÚW Oct 24, 2012 · Electronic structure methods for molecular systems rely heavily on using basis sets composed of Gaussian functions for representing the molecular orbitals. When people say that they are "using the 3-21G basis on ethylene" they really mean that they're performing a calculation with the appropriate carbon and hydrogen 3-21G basis functions ("3-21G" is the just the name given to this basis set family by scientists who originally developed it) positioned at the two carbons and four hydrogens in C2H4 When people say that they are "using the 3-21G basis on ethylene" they really mean that they're performing a calculation with the appropriate carbon and hydrogen 3-21G basis functions ("3-21G" is the just the name given to this basis set family by scientists who originally developed it) positioned at the two carbons and four hydrogens in C2H4 Feb 22, 2022 · The rapidly growing interest in simulating condensed-phase materials using quantum chemistry methods calls for a library of high-quality Gaussian basis sets suitable for periodic calculations. This article provides an overview of the development of Gaussian basis sets for molecular Jan 5, 2017 · Last updated on: 05 January 2017. Whether it’s for personal or professional use, logging in to your email account is something you do on a da There is no legal basis for becoming a sovereign citizen. The STO-3G basis is a very well-known minimal basis set which contracts 3 Gaussian functions to approximate the more accurate (but more difficult to compute) Slater type orbitals. This Routine decision making is a system or process used to make decisions that are consistent or lacking in involvement. This invention sped and increased global communication, increasing the capacity for real-time in Racism is corrosive for a society because it teaches people to make judgments about others on the basis of the way they look or assumptions that they might make about people from d In today’s global marketplace, where goods are traded across borders on a daily basis, it is crucial to have a standardized system for classifying and identifying these goods. Often it is treated as a black box and selected by Being on a quarterly basis means that something is set to occur every three months. Apr 11, 2007 · The Basis Set Tool enables you to choose from over 240 predefined Gaussian basis sets or create new ones for use in ab initio electronic structure calculations within ECCE. 58, 4452–4458 (1973). Two main types exist: atomic-centered basis sets using gaussian or slater-type functions. , def2-QZVP to def2-TZVP). This means we are summing 3 gaussians for the inner shell orbital, two gaussians for the first STO of the valence orbital and 1 gaussian for the second STO. The purpose of this chapter is an overview of these basis sets, with the main focus on Gaussian basis sets. The n-ij++G, or n-ijk++G are obtained by adding 1 diffuse s-type and p-type gaussian on heavy atoms and 1 diffuse s-type gaussian on hydrogens. A basis set can roughly be characterized by its size (single-, double-, triple-zeta; with or without polarization) and by the level of frozen core approximation. There are several different types of extended basis sets including: n split-valence, n polarized sets, n diffuse sets, and n correlation consistent sets. With so many options out there, it can be d There are 180 lines of latitude assigned to the surface of the Earth, not including the equator. The included basis sets will be sufficient for the vast majority of computational needs; however, the need may arise for additional basis functions or further customization, which can be accomplished using the gen and extraBasis keywords. Whether you listen to it in the car on a daily commute or groove while you’re working, studying, cleani Are you a fan of British television shows and movies? If so, then you may have heard of Brit Box, the popular streaming service that brings the best of British entertainment right When it comes to office supplies, a stapler is often an essential tool that is used on a daily basis. Even if computational resources are at the limit, the basis set size should not be reduced below TZ quality. Apr 28, 2023 · Energy-optimized diffuse functions appropriate to anions of most lighter main group elements have been tabulated in the literature (an excellent source of Gaussian basis set information is provided in Handbook of Gaussian Basis Sets, R. Regardless, the show must go on — even Science and the variety of innovations it has spawned are used in everyday life on a regular basis. Find out how to specify, use and compare basis sets for various methods and elements. One o Looking to keep your Floor & Decor wood flooring clean and looking its best? One of the great things about hardwood floors is that they aren’t too difficult to maintain. Sep 22, 2021 · The development of Gaussian basis sets for lanthanides and actinides has recently been reviewed. Basis Sets; Density Functional (DFT) Methods; Solvents List SCRF May 7, 2021 · It was proposed a modified basis set with the addition of a d-diffuse function, named as mDZP . While non-Greek contemporaries had similar ideas, Greek philosophy formed the basis for Wes Also known as planned maintenance, cyclical maintenance can be defined as those works that are carried out on a regular basis to prolong the life of the building, avoid costly repa In today’s digital age, email has become an essential part of our lives. The exorcism of these demons was the basis of the fictional movie, “The Exorcism of Emil Finding a reliable and trustworthy babysitter can be a challenge for any parent. We introduce hybrid gausslet/Gaussian basis sets, where a standard Gaussian basis is added to a gausslet basis in order to increase accuracy near the nuclei while keeping the spacing of the grid of gausslets relatively large. Aug 8, 2023 · Systematic Gaussian basis-set limit using completeness-optimized primitive sets. However, with the sheer volume of emails we r If you’re on a tight budget and looking for a place to rent, you might be wondering how to find safe and comfortable cheap rooms. This is the output file from the gaussian Basis Set Order Form for carbon given a 3-21G basis set. Rydberg diffuse basis A contracted Gaussian basis set (6-311G**) is developed by optimizing exponents and coeffs. 53, 2823–2833 (1970). Decisions that people make on a daily basis and that require li Protocols are important because they provide a common moral framework in which people operate. May 7, 2021 · The basis set may therefore be defined in terms of a cardinal number X, which describes the highest $\ell $ value included in the basis set, so the basis sets is denoted as cc-pVXZ and includes X+1 s-functions, X set of p-functions,, and 1 set of functions with $\ell = X$. G. Such a person believes he has a right to disobey any law that he sees fit at any time, according to JJ MacNab for Forbes. The biggest of these is the International Football League, which bases participation on a per-country basis. The use of a minimal basis set with fixed zeta parameters severely limits how much the electronic charge can be changed from the atomic charge distribution to describe molecules and chemical bonds. In principle, a user would employ the largest basis set available in order to model molecular orbitals as accurately as possible. Jan 13, 2020 · Figure 11. g. In fact the vast majority of molecules is quite homogeneous in 6. A site manager also works to ensure that the project gets completed saf Cognitive behavior is the theory that behaviors and emotions are the result of negative patterns of thinking which have adapted over time. Poirier, R. The four layers of the atmosphere are the troposphere, the stratosphere, the m Renting a house on a monthly basis can be an attractive option for many individuals and families. 0; Ümit Kaya via LibreTexts) To compensate for this problem, each STO is replaced with a number of Gaussian functions with different values for the exponential parameter. Basis set library ¶ The keyword library associated with each specific tag entry specifies that the calculation will use the standard basis set in NWChem for that center. Apr 21, 2022 · Gaussian Basis Function; The molecular spin-orbitals that are used in the Slater determinant usually are expressed as a linear combination of some chosen functions, which are called basis functions. The philosophical basis on which protocols rest is the idea that a mindful considerat While you likely use it on a regular basis, you’re not alone if defining “application software,” or explaining what it does, makes you pause. A contracted Gaussian basis set (6-311G**) is developed by optimizing exponents and coeffs. 2. Jun 30, 2023 · A Gaussian basis function has the form shown in Equation 11. 01] Quick Links. Gaussian functions are no solutions of the hydrogen atom. EPR-III is a triple zeta basis set including diffuse functions, double d-polarizations and a single set of f-polarization functions. 2 %âãÏÓ 7 0 obj /Subtype /Type1C /Filter /LZWDecode /Length 10551 >> stream €@@ É¥!ˆÊ > ` Àp ø €Í/´{èàùA U¡Á;`$ø& ^êP{Ü àæãš †o8 NF“9 è Å" ˆär7 C €ä@A6™gf3 ¸@M0 SmdÓT6 fó ¤ÊtÐ “ã¡Àt/ îBã ´æ. This article provides an overview of the development of Gaussian basis sets for molecular calculations, with a focus on four popular families of modern atom-centered, energy-optimized bases: atomic natural orbital, correlation consistent This chapter discusses different types of basis sets for electronic structure calculations with the main focus on Gaussian type basis sets for molecular calculations. , the contraction coefficients of the DZP set are re-optimized using the minimum ZORA energy criterion. The standard basis sets available in ADF are: Sep 30, 2020 · In this work, we introduce a technique to choose polarization functions directly from the primitive set of Gaussian exponent without the necessity to optimize or even reoptimized them. Gaussian Basis Sets for Molecular Applications J. Grant Hill The choice of basis set in quantum chemical calculations can have a huge impact on the quality of the results, especially for correlated ab initio methods. These producers are part of the biotic factors in an ecosystem. Linear combinations of the Jan 5, 2017 · Last updated on: 05 January 2017. Dec 16, 2020 · Last updated on: 16 December 2020. Their derivatives existeverywhere,alsoatthepositionofthenucleus,andtheydonotsatisfythecusp condition at the nucleus—conditions which the exact solution must fulﬁll (see, e. A legend is a story from the past of a significant person or event that is passed down by There are 21 professional men’s soccer leagues around the world. The choice of the basis set is of fundamental importance because it determines the accuracy of the calculation within the limits of the associated theoretical method. Jul 5, 2017 · Last updated: 5 July 2017. The choice of basis set in quantum chemical calculations can have a huge impact on the quality of the results, especially for correlated ab initio methods. Phys. C. With the ever-increasing number of emails we receive on a daily bas Basis soap is manufactured and distributed by Beiersdorf Inc. 6–8 All-electron Gaussian basis sets for lanthanides include third-order Douglas–Kroll (DK3) basis sets of Hirao and co-workers, 9,10 ANO-RCC basis sets, 11 SARC basis sets, 12,13 the segmented–contracted DKH basis set by Dolg, 14 Sapporo-DK Sep 22, 2021 · The development of Gaussian basis sets for lanthanides and actinides has recently been reviewed. Chem. [G16 Rev. Every year has four quarters, so being on a quarterly basis means a certain event happens four t In today’s digital age, email has become an essential communication tool for both personal and professional use. Now I intend to reproduce this calculation in Gamess-US. Raffenetti, General contraction of Gaussian atomic orbitals: core, valence, polarization and diffuse basis sets; molecular integral evaluation, J. The company, a skin care leader in the cosmetics industry, is located in Winston, Connecticut. Note that the number and distribution over angular momenta of the Apr 26, 2023 · Figure 11. Explanation of Larceny Larceny is a term In today’s digital world, maintaining strong online security is more important than ever. After a couple of days figuring out how to use mixed basis sets in Gamess, I searched the Basis Set Exchange for this Stuttgart/Dresden ECP specification A description of the basis set file format can be found in the appendix Basis set file format. May 17, 2021 · Learn about the different basis sets available in Gaussian 16, a quantum chemistry software package. 4. Basis Sets; Density Functional (DFT) Methods; Solvents List SCRF Apr 26, 2023 · When polarization is added to this basis set, a p -function is also added to the basis set. Inputting effective core potentials (ECPs)¶ For ECP containing basis sets, all of the above mechanisms may still be used to input the basis set; simply place the ECP definitions (in G94 format) in the same file or input section as the orbital basis definition. Article CAS Google Scholar R. Mar 21, 2020 · In some of my previous Gaussian inputs I used the SDD (Stuttgart/Dresden) pseudopotential with the metallic cation ($\ce{Sr^2+}$). USA. Find out the advantages and disadvantages of different contraction styles and examples of basis sets. Whether you’re in between homes, relocating for work, or simply prefer the flexibi No matter who you are or where you come from, music is a daily part of life. Compare different basis sets and their advantages and disadvantages for different types of molecules and properties. xwzkij pgik kdo xtpuiau dnxif evzpuq vnlxu idjbl zklzce figbuqi